Rotational Spectra of Rigid Rotor Molecules
Rotational Energies The classical energy of a freely rotating molecule can be expressed as rotational kinetic energy. where x, y, and z are the principal axes of rotation and I x represents the moment of inertia about the x-axis, etc. In terms of the angular momenta about the principal axes, the expression becomes. The formation of the Hamiltonian for a freely rotating molecule is accomplished ...
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